CO2 Purification and Liquefaction Plants

Capturing waste streams of carbon dioxide and putting them to good use.

Balancing Rising Demand for Energy with Climate Mitigation Pressures

As global demand for energy rises, so does the need for solutions to minimize the carbon balance of fossil fuel combustion. One possible way to balance conflicting needs lies in reducing combustion-induced carbon emissions with plants that capture CO2 from flue gases and then purify and liquefy the gas for other applications. Here at Linde, we have developed a wide portfolio of both customized and standardized CO2 plants to meet all volume, purity and time-to-solution needs.

Complementing our customized offering, we deliver a range of modular plants. These are designed to maximize cost efficiencies, and reduce risk and production time through standardization and pre-testing, while still giving you the flexibility you need to adapt to variations in feed gas sources and product requirements. Design highlights include a compact footprint and ease of maintenance. Being both plant supplier and operator, Linde has the capability to feed the operational experience back into future plant design. Each client can profit from these continuous improvements.

CO2 purification and liquefaction plant; CO2 storage; Client: Vattenfall

Minimum Operating Costs

Our CO2 plants are designed for the highest levels of energy efficiency. Ease of maintenance and automated operations further reduce operating costs. A distributed control system (DCS) or programmable logic controller (PLC) dynamically adjust the process to meet changes in the feed gas composition or plant load.

Maximum Availability and Ease of Maintenance

Offering exceptional availability rates close to 100%, all of our plants are engineered for excellence, featuring premium components to ensure maximum operational uptime. Easy accessibility to all components simplifies maintenance. In addition, we deliver spare parts and can also look after maintenance and after-sales support.

Advanced Flexibility

We engineer our CO2 purification and liquefaction plants to give you the flexibility you require. For instance, operational capacity can be easily adjusted to the desired output level. The plant design can be adapted to all variations in feed gas sources and be started up and shut down within a matter of hours.

Remote Control

To increase manageability even further, our plants come with an optional dedicated port that can be connected to a communication board for remote control. Plants can even be powered up and shut down in remote mode. In addition, fully automated product analysis, truck loading and weighing equipment are available.

Complementary Services

Rounding out our offering of CO2 plants, we also offer a range of financing and aftersales support services as well as remote management through our Remote Operating Centers (ROCs).

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Technology Leadership

In some industry sectors a term CPU (CO2 Processing Unit) has been established. It means in general an assembly or a combination of different processing units (e. g. raw gas pre-conditioning, compression, scrubbing, purification/polishing, rectification, …), which can be a part of CO2 plant depending on raw gas composition and CO2 product requirements.

All of our CO2 plants reflect our long-standing experience and technology leadership in cryogenic systems. The purification and liquefaction process flow is outlined in the image left.

Flow diagram of a CO2 purification and liquefaction plant

Pre-Cooling and Compression

This unit cools down the water-saturated feed gas and then separates the water. The cooled gas is sent to the CO2 compressor to increase the pressure up to operating conditions. Boiloff gas from the storage tanks can also be recycled to the compressor. Oil filters and various adsorbers can be added downstream as required to remove additional components such as hydrogen sulfide (H2S) or trace impurities.

Scrubbing

The CO2 gas is fed into the scrubber unit to wash and cool down the gas. This is also where water-soluble components such as alcohols are removed.

Drying and Adsorption

The remaining water and traces of other chemical components are removed from the gas stream in the interchangeable dryers. Depending on requirements, various adsorbers and filters are installed downstream in order to remove further components such as carbonyl sulfide (COS).

Liquefaction

The dry CO2 gas passes through a reboiler followed by the CO2 distillation column. The gas leaving the column at the top contains the inert components. The liquid CO2 product drawn off the bottom is sent to the storage tank or vaporised for various on-site solutions.

Storage System and Loading Facilities

The liquefied CO2 is stored in pressurized tanks. For transportation purposes, it is pumped through the respective loading facilities into trucks, railway cars and ships. For gaseous on-site applications, the CO2 is pressurized by means of additional compressors connected to the pipeline network.

References

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